Are you sure, that your calculation is correct? Just check the PF deduction before 1.9.2014 (as the ceiling is Rs. 6,500 at that time). He can check his PF passbook in the UAN Portal to know the estimated withdrawal money.
He need to apply using Form 19 and Form 10 C. In Form 10C, he need to opt for Scheme Certificate. (He can't opt for withdrawal of Pension Amount, as it will get rejected). He should provide the family details and nomination details in the respective column. He will receive Scheme Certificate through post. He need to keep that Scheme Certificate safe till his age of 58 years. During that time, he need to submit this Scheme Certificate to the PF Department.
19th October 2016 From India, Chennai