I hope you will be today a successful ,happy worker.I will be more glad to hear that you have reached CEO level.
Now for others, who have related confusion and query let me say that ...before entering the professional life you need to observe your interests and expertise.If still there is a tie then you can try doing an internship,this will make things more clear .Passion towards a job really adds to one's growth and that of organization's.
But, if money is your priority then different jobs come with different pay scales depending on the organization's budget and how much they want to spend on a resource.Same job posts in different organizations may have different pay scales so you need to do research within your targeted area.
As far as becoming a CEO is concerned if you have investment and you are smart you can have a startup and you will be the boss of that startup.This is the easiest shortcut towards CEO post otherwise this will definitely require a lot of effort and of course luck :)