I believe that the employee in question joined sometime after September 1, 2014. At the time of joining, his salary was above Rs 15,000. Therefore, the then-employer did not cover him under EPS, but the entire contribution of 12% payable by him was paid to EPF along with the employee's contribution of 12%. Now he has changed jobs and joined your company. His salary is still higher than Rs 15,000. Your question is: can you pay the contribution payable (8.33%) to the pension fund? The answer is NO. You can continue with PF, with the same UAN, and you can pay your contribution exclusively to the Provident Fund only. Very simple, an employee who joined after September 1, 2014, whose salary exceeds Rs 15,000, cannot be a member of the Pension Scheme.