An intern is not defined as such in Indian labour law.
Therefore, they are employees from the first day they work for you.
If you are taking apprantices as approved by the apprantice advisor, then they are not employees under the rules as long as you adhere to the terms and period specified by the apprantice advisor.
If your certified standing orders have a provision for apprantices (other than those under apprantices act), then those recruited under the standing orders as apprantices will not be employees. The standing orders will generally restrict it between 1 and 2 years.
Any other intern is an employee from day 1