Hi,
To date, there is no online option available for PF withdrawal. Currently, you can only apply using Forms 19 (UAN) & 10C (UAN) and submit them directly to RPFC without the involvement of the employer.
Regarding TDS on EPF, if your PF amount exceeds Rs. 50,000, then you must submit Form 15G (two copies) along with the withdrawal forms.
Regards,
Balwant Chouhan