Dear Friend,
As per the law, accident on the way from office to home is not considered as accident on duty as it is not clear in the Act.
You may refer the the Employee State Insurance Act, 1948, Section 2(8) "employment injury" means a personal injury to an employee caused by accident or an occupational disease arising out of and in the course of his employment, being an insurable employment, whether the accident occurs or the occupational disease is contracted within or outside the territorial limits of India.
And further, as per Section 46(1) Subject to the provisions of this Act, the insured persons their dependents or the persons hereinafter mentioned, as the case may be, shall be entitled to the following benefits, namely :-
(C) periodical payments to an insured person suffering from disablement as a result of an employment injury sustained as an employee under this Act and certified to be eligible for such payments by an authority specified in this behalf by the regulations (hereinafter referred to as disablement benefit).
It is better you speak with an expert.
Regards.