Hi Rama,
As you have mentioned that the employee's basic salary is more than Rs. 6500/- and upon joining a new company, they deduct P.F. for all employees, in that case, certainly, the new company will deduct the P.F.
There is Form No. 11, which is to be filled out along with Form No. 2 (Nomination & Declaration form). In Form No. 11, we gather information about whether the new employee was a member of the P.F. in the last company. If the employee was a member of the P.F. in the last company, then it is the obligation of the new company to deduct the P.F. up to Rs. 6500/- (Basic + DA + Retaining Allowance, if any).
Rajiv Singh