As for as pf concerned, there is no probation period etc., from the day one of employment,one employee is elegible. He can withdraw only after two months time from the date of leaving/relief. As for as the family pension contribution (employer's share of 8.33%, one can withdraw only after the minimum period of 6 month membership.) Whatever may be the condition,it is strongly advised that NOT TO WITHDRAW THE PF AMOUNT AND SUGGESTED STRONGLY TO GET TRANSFERED TO THE NEW JOB GOING TO BE ASSIGNED BY YOU.